氯化[吡啶-2,6-二(2,1-亚苯基)]金 

氯化[吡啶-2,6-二(2,1-亚苯基)]金
IUPAC名
(SP-4-2)-Chloro[(2,6-pyridinediyl-κN)di(2,1-phenylene-κC)]gold
识别
CAS号 211680-78-3  ✓
SMILES
性质
化学式 C17H11AuClN
摩尔质量 461.7 g·mol−1
若非注明,所有数据均出自一般条件(25 ℃,100 kPa)下。

氯化[吡啶-2,6-二(2,1-亚苯基)]金是一种配位化合物,化学式为C17H11AuClN,它可由氯化[2-(6-苯基-2-吡啶基)苯基]汞和氯金酸钾(KAuCl4)在乙腈中回流反应得到。[1]它和三氟乙酸银在二氯甲烷中反应,氯可以被三氟乙酸根取代。[1]它在室温下和1,3,5-三氮杂-7-磷杂金刚烷(PTA)反应,得到[C17H11NAu-PTA]PF6[2]在相应的反应条件下,也能得到含有新的Au-C键的有机金化合物。[3][4]

  1. ^ 1.0 1.1 Wai-Pong To, Glenna So Ming Tong, Chi-Wah Cheung, Chen Yang, Dongling Zhou, Chi-Ming Che. Luminescent Cyclometalated Gold(III) Alkyl Complexes: Photophysical and Photochemical Properties. Inorganic Chemistry. 2017-05, 56 (9): 5046–5059 [2019-10-15]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.7b00180 (英语). 
  2. ^ Sophie Jürgens, Valeria Scalcon, Natalia Estrada-Ortiz, Alessandra Folda, Federica Tonolo, Christian Jandl, Duncan L. Browne, Maria Pia Rigobello, Fritz E. Kühn, Angela Casini. Exploring the C^N^C theme: Synthesis and biological properties of tridentate cyclometalated gold(III) complexes. Bioorganic & Medicinal Chemistry. 2017-10, 25 (20): 5452–5460 [2019-10-15]. doi:10.1016/j.bmc.2017.08.001. (原始内容存档于2019-08-26) (英语). 
  3. ^ Vonika Ka-Man Au, Keith Man-Chung Wong, Nianyong Zhu, Vivian Wing-Wah Yam. Luminescent Cyclometalated N -Heterocyclic Carbene-Containing Organogold(III) Complexes: Synthesis, Characterization, Electrochemistry, and Photophysical Studies. Journal of the American Chemical Society. 2009-07, 131 (25): 9076–9085 [2019-10-15]. ISSN 0002-7863. doi:10.1021/ja9027692 (英语). 
  4. ^ Vonika Ka-Man Au, Nianyong Zhu, Vivian Wing-Wah Yam. Luminescent Metallogels of Bis-Cyclometalated Alkynylgold(III) Complexes. Inorganic Chemistry. 2013-01-18, 52 (2): 558–567 [2019-10-15]. ISSN 0020-1669. doi:10.1021/ic3007519 (英语). 



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