四氯化鎝(化學式:TcCl4),為唯一稳定的鎝的氯化物。它是红色晶体,可以很容易地在氮气或氯气中于300°C左右以升华法提纯[1]。
它在1957年被发现,1965年得到结构表征。[2]
- ^ Johnstone, Erik V.; Poineau, Frederic; Forster, Paul M.; Ma, Longzou; Hartmann, Thomas; Cornelius, Andrew; Antonio, Daniel; Sattelberger, Alfred P.; Czerwinski, Kenneth R. Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides. Inorganic Chemistry. 2012-07-09, 51 (15): 8462–8467. PMID 22775538. doi:10.1021/ic301011c (英语).
- ^ Frederic Poineau, Erik V. Johnstone, Kenneth R. Czerwinski, Alfred P. Sattelberger. Recent Advances in Technetium Halide Chemistry. Accounts of Chemical Research. 2014-02-18, 47 (2): 624–632 [2021-04-16]. ISSN 0001-4842. doi:10.1021/ar400225b. (原始内容存档于2020-07-30) (英语).